27646-80-6, Name is 2-Methyl-2-(methylamino)propan-1-ol, molecular formula is C5H13NO, Product Details of 27646-80-6, belongs to alcohols-buliding-blocks compound, is a common compound. In a patnet, author is Huang, Lei, once mentioned the new application about 27646-80-6.
MOF-derived well-structured bimetallic catalyst for highly selective conversion of furfural
Selective conversion of furfural can produce some important chemical intermediates. However, it is a challenge to design suitable catalysts due to the complex reaction route. A series highly dispersed Co-Ni alloy NPs embedded in porous nitrogen-containing carbon matrix multifunctional catalysts (xCo-yNi@NC) were prepared by pyrolysis of MOF template. The characterization results showed that Co-Ni alloy presented strong bimetallic synergistic effect and introduction of N species influenced the physicochemical properties of the catalyst, hence promoted the catalytic performance. Moreover, Lewis acid sites provided by metal oxide species can polarize the C=O bond via lone pair electrons on the oxygen atom, which contribute to furfuryl alcohol formation and accelerate furfuryl alcohol rearrangement to 4-hydroxy-2-cycloentenone. In addition, the solvent played an important role in the product distribution. Under the optimized reaction conditions, 99.0% furfuryl alcohol yield was obtained in methanol solvent, while 92.5% cyclopentanone yield was obtained in water solvent over 2Co-1Ni@NC.
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Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts