Chemistry is an experimental science, Recommanded Product: 6920-22-5, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 6920-22-5, Name is Hexane-1,2-diol, molecular formula is C6H14O2, belongs to alcohols-buliding-blocks compound. In a document, author is Vijeta, Arjun.
Visible-Light Promoted C-O Bond Formation with an Integrated Carbon Nitride-Nickel Heterogeneous Photocatalyst
Ni-deposited mesoporous graphitic carbon nitride (Ni-mpg-CNx) is introduced as an inexpensive, robust, easily synthesizable and recyclable material that functions as an integrated dual photocatalytic system. This material overcomes the need of expensive photosensitizers, organic ligands and additives as well as limitations of catalyst deactivation in the existing photo/Ni dual catalytic cross-coupling reactions. The dual catalytic Ni-mpg-CNx is demonstrated for C-O coupling between aryl halides and aliphatic alcohols under mild condition. The reaction affords the ether product in good-to-excellent yields (60-92 %) with broad substrate scope, including heteroaryl and aryl halides bearing electron-withdrawing, -donating and neutral groups. The heterogeneous Ni-mpg-CNx can be easily recovered from the reaction mixture and reused over multiple cycles without loss of activity. The findings highlight exciting opportunities for dual catalysis promoted by a fully heterogeneous system.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 6920-22-5, in my other articles. Recommanded Product: 6920-22-5.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts