Application of 1-Hydroxymethyl-3-cyclopentene

At the same time, in my other blogs, there are other synthetic methods of this type of compound,25125-21-7, 1-Hydroxymethyl-3-cyclopentene, and friends who are interested can also refer to it.

Adding a certain compound to certain chemical reactions, such as: 25125-21-7, 1-Hydroxymethyl-3-cyclopentene, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound, Recommanded Product: 25125-21-7, blongs to alcohols-buliding-blocks compound. Recommanded Product: 25125-21-7

To a solution of cyclopent-3-enylmethanol 146-2 (4.0 g, 41 mmol) in dichloromethane (150 mL) at 0C was added 3-chloroperbenzoic acid (10 g, 45 mmol, 77% purity) by portion. The reaction was stirred overnight. Dichloromethane (150 mL) was added. The organics was washed with sodium thiosulfate (12 g in 10 mL water), followed by saturated NaHCCb (40 mL). This was repeated till all the remaining 3-chloroperbenzoic acid was washed away. The organic was dried over MgSC. Evaporation of solvent gave a mixture of cis- and trans- 6- oxabicyclo[3.1.0]hexan-3-ylmethanol 146-3 (2.6 g, 57 %) as a yellow oil. GC-MS: m/z 114 (5) (M+), 95 (15), 88 (100), 81 (15).

At the same time, in my other blogs, there are other synthetic methods of this type of compound,25125-21-7, 1-Hydroxymethyl-3-cyclopentene, and friends who are interested can also refer to it.

Reference:
Patent; ARBUTUS BIOPHARMA CORPORATION; MENDEZ, Patricia; SYMONDS III, William T.; DIETERICH, Douglas; (290 pag.)WO2019/51257; (2019); A2;,
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts