The origin of a common compound about Related Products of 13826-35-2

At the same time, in my other blogs, there are other synthetic methods of this type of compound,13826-35-2, (3-Phenoxyphenyl)methanol, and friends who are interested can also refer to it.

Related Products of 13826-35-2, Researchers who often do experiments know that organic synthesis is a process of preparing more complex target molecules from simple raw materials through one or more chemical reactions. Generally, it requires fewer steps,and cheap raw materials. 13826-35-2, name is (3-Phenoxyphenyl)methanol. A new synthetic method of this compound is introduced below.

General procedure: All the reactions were carried out in a multi-reactor (Carousel 12 station, RADLEYS). Typically, 0.5 mmol morpholine (43 mg), 1.0 mmol benzyl alcohol (108 mg), 50 mg Au/HT (1.9 mol % Au), and 5 mL o-xylene were added to a 40 mL glass vessel. Then, the reaction mixture was stirred (310 rpm) at 90 C under argon. After 24 h, it was cooled down to room temperature. ?20 mL ethyl acetate was added to dissolve the reaction mixture and filtrated with celite to remove the solids. Then the ethyl acetate and solvent were removed under vacuum and a yellow liquid was obtained. It was further purified using column chromatography (ethyl acetate / petroleum ether = 2/3, v/v; Silica Gel: 200-300 mesh; Rf = 0.17) to obtain the pure product as a white solid.

At the same time, in my other blogs, there are other synthetic methods of this type of compound,13826-35-2, (3-Phenoxyphenyl)methanol, and friends who are interested can also refer to it.

Reference:
Article; Zhu, Jiangling; Zhang, Yan; Shi, Feng; Deng, Youquan; Tetrahedron Letters; vol. 53; 25; (2012); p. 3178 – 3180;,
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts