Related Products of 111-45-5, The major producers of chemicals have been the Europe, Japan and China. Due to the growing call for a cleaner, greener environment, people will have to find innovative ways to maintain their relevance. Here is a compound 111-45-5, name is 2-(Allyloxy)ethanol. This compound has unique chemical properties. The synthetic route is as follows.
To a solution of sodium hydroxide (4.6 g, 115 mmol) in water (25 mL) was added a solution of ethyleneglycol monoallyl ether (10.0 g, 98 mmol) in THF (50 mL) at 0 C (ice/water bath). A solution of p-toluene sulfonyl chloride (17.9 g, 93 mmol) in THF (40 mL) was added dropwise to the alkaline solution at 0 oC. After completion of addition, the reaction mixture was stirred for 1 h at room temperature and poured into ice/water. The organic materials were extracted with hexane and hexane layer was washed with brine, dried with MgSO4 , and evaporated to leave a residue which was distilled under vacuum to give 22.4 g of 2-(p-tolylsulfonyloxy)ethyl propenyl ether (1b) as a colorless oil in 93% yield (22.4 g).
According to the analysis of related databases, 111-45-5, the application of this compound in the production field has become more and more popular.
Reference:
Article; Kultyshev, Roman G.; Kawanishi, Yuji; Nishioka, Masateru; Miyazawa, Akira; Synthetic Communications; vol. 44; 4; (2014); p. 556 – 563;,
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